Analytical Methodology · Lot Release

How we verify.

No lot leaves the facility unverified. Every batch is characterised by two orthogonal analytical methods — one for purity, one for identity — under ISO/IEC 17025 accredited methodology.

Methods · Per Lot
02
Purity Threshold
>99%
Mass Accuracy
± 0.4 ppm
Release Audit
100%
Method 01 · Purity
ISO/IEC 17025 · §7.2.1
HPLC

High-Performance Liquid Chromatography.

For chromatographic purity verification at thresholds exceeding 99%.

Reverse-phase HPLC separates peptide components by their hydrophobic interaction with a C18 stationary phase. A linear gradient of acetonitrile in 0.1% trifluoroacetic acid carries each species through the column at a characteristic retention time, producing a chromatogram from which purity is quantified by area-percent integration of the principal peak relative to all detected species.

Sample Chromatogram · Lot HX-7741
214 nm · 1.0 mL/min
Instrument
Acquity UPLC I-Class
Column
C18 · 1.7 µm
Detection
UV · 214 nm
Acceptance
≥ 99.0%
Method 02 · Identity
ISO/IEC 17025 · §7.2.2
MS

Mass Spectrometry.

For molecular identity confirmation at parts-per-million mass accuracy.

Each peptide is ionised under electrospray and resolved on an Orbitrap-class mass analyser. The observed monoisotopic mass is compared against the theoretical value computed from the peptide's amino-acid sequence; agreement within ± 5 ppm constitutes confirmation of molecular identity.

Isotopic envelope analysis simultaneously confirms charge state and resolves any co-eluting isobaric species, providing orthogonal verification to the chromatographic separation.

Mass Spectrum · Lot HX-7741
Orbitrap Eclipse · 120k FWHM
Instrument
Orbitrap Eclipse
Ionisation
ESI · Positive
Resolution
120,000 FWHM
Mass Accuracy
± 0.4 ppm
03 · Workflow

The release workflow.

  1. 01

    Synthesis Completion

    Cleavage from resin, lyophilisation, and packaging into individually labelled vials.

  2. 02

    Sample Withdrawal

    A representative sample is withdrawn from each lot under cleanroom conditions.

  3. 03

    HPLC Purity Analysis

    Chromatographic separation and area-percent quantification against an internal standard.

  4. 04

    Mass Spectrometric ID

    Monoisotopic mass measurement and isotope envelope confirmation.

  5. 05

    Dossier Compilation

    Lot-specific Certificate of Analysis generated, signed, and archived to LIMS.

  6. 06

    Release & Shipment

    Approved lots cleared for distribution; rejected lots quarantined for root-cause investigation.

View All Lot Certificates

COA Library access.

Every lot we have ever released, with its certificate of analysis, indexed by product category.

COA Library